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129.听听Ke, J.; Lee, W.-C. C.; Wang, X.-X.; Wang, Y.; Wen, X.; Zhang, X. P. 鈥淢etalloradical Activation of In Situ-Generated听伪听-Alkynyldiazomethanes for Asymmetric Radical Cyclopropanation of Alkenes鈥澨�J. Am. Chem. Soc.听2022,听144, 2368鈥�2378. []

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115.听听Lang, K.; Torker, S.; Wojtas, L.; Zhang, X. P. 鈥淎symmetric Induction and Enantiodivergence in Catalytic Radical C鈥揌 Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution鈥澨�J. Am. Chem. Soc.听2019,听141, 12388鈥�12396. []

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112.听听Wen, X.; Wang, Y.; Zhang, X. P. 鈥淓nantioselective Radical Process for Synthesis of Chiral Indolines by Metalloradical Alkylation of Diverse C(sp3)-H Bonds鈥澨�Chem. Sci.听2018,听9, 5082鈥�5086. []

111.听听Wang, Y.; Wen, X.; Cui, X.; Zhang, X. P. 鈥淓nantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation鈥澨�J. Am. Chem. Soc.听2018,听140, 4792鈥�4796. []

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109.听听Wang, Y.; Zhang, X. P. 鈥淸Co(3,5-Di-t-Bu-Xu(2鈥�-Naph)Phyrin)]鈥澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02203. []

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106.听听Wang, Y.; Zhang, X. P. 鈥淸Co(2,6-DiMeO-ZhuPhyrin)]鈥澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02200. []

105.听听Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. 鈥淎symmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis鈥澨�J. Am. Chem. Soc.听2017,听139, 9164鈥�9167. []

104.听听Xu, X.; Wang, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. 鈥淢etalloradical Activation of听伪-Formyldiazoacetates for Catalytic Asymmetric Radical Cyclopropanation of Alkenes鈥澨�Chem. Sci.听2017,听8, 4347鈥�4351. []

103.听听Wang, Y.; Wen, X.; Cui, X.; Wojtas, L.; Zhang, X. P. 鈥淎symmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis鈥澨�J. Am. Chem. Soc.听2017,听139, 1049鈥�1052. []

102.听听Pegis, M. L.; McKeown, B. A.; Kumar, N.; Lang, K.; Wasylenko, D. J.; Zhang, X. P.; Raugei, S.; Mayer, J. M. 鈥淗omogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions鈥澨�ACS Cent. Sci.听2016,听2, 850鈥�856. []

101.听听Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. 鈥淚ntramolecular Radical Aziridination of Allylic Sulfamoyl Azides via Co(II)-Based Metalloradical Catalysis: Effective Construction of Strained heterobicyclic Structures鈥澨�Angew. Chem. Int. Ed.听2016,听55, 11604鈥�11608. []

100.听听Lu, H.-J.; Lang, K.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. 鈥淚ntramolecular 1,5-C(sp3)鈥揌 Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides鈥澨�Chem. Sci.听2016,听7, 6934鈥�6939. []

99.听听Liu, Q.-J.; Wang, L.-J.; Kang, Q.-K.; Zhang, X. P.; Tang, Y. 鈥淐y-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals鈥澨�Angew. Chem. Int. Ed.听2016,听55, 9220鈥�9223. []

98.听听Cui, X.; Zhang, X. P. 鈥淐鈥揅 Bond Formation Using Carbenes鈥� In听Science of Synthesis: Catalytic Transformations via C鈥揌 Activation听series; eds. Yu, J. -Q.; Thieme,听2016, Vol. 2, pp. 63鈥�94. []

97.听听Liu, Q.-J.; Yan, W.-G.; Wang, L.-J.; Zhang, X. P.; Tang, Y. 鈥淥ne-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles鈥澨�Org. Lett.听2015,听17, 4014鈥�4017. []

96.听听Goswami, M.; Lyaskovskyy, V.; Domingos, S. R.; Buma, W. J.; Woutersen, S.; Troeppner, O.; Ivanovic-Burmazovic, I.; Lu, H.-J.; Cui, X.; Zhang, X. P.; Reijerse, E. J.; DeBeer S.; van Schooneveld, M. M.; Pfaff, F.; Ray, K.; de Bruin, B. 鈥淐haracterization of Porphyrin-Co(III)-鈥楴itrene Radical鈥� Species Relevant in Catalytic Nitrene Transfer Reactions鈥澨�J. Am. Chem. Soc.听2015,听137, 5468鈥�5479. []

95.听听Subbarayan, V.; Jin, L.-M., Cui, X.; Zhang, X. P. 鈥淩oom Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis鈥澨�Tetrahedron Lett.听2015,听56, 3431鈥�3434. []

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93.听听Jin, C.-Y., Decker, A. M.; Huang, X.-P.; Gilmour, B. P.; Blough, B. E.; Roth, B. L.; Hu, Y.; Gill, J. B.; Zhang, X. P. 鈥淪ynthesis, Pharmacological Characterization, and Structure-Activity Relationship Studies of Small Molecular Agonists for the Orphan GPR88鈥澨�ACS Chem. Neurosci.听2014,听5, 576鈥�587. []

92.听听Lu, H.-J.; Li, C.-Q.; Jiang, H.-L.; Lizardi, C. L.; Zhang, X. P. 鈥淐hemoselective Amination of Propargylic C(sp3)鈭扝 Bonds via Co(II)-Based Metalloradical Catalysis鈥澨�Angew. Chem. Int. Ed.听2014,听53, 7028鈥�7032. []

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88.听听Paul, N. D.; Mandal, S.; Otte, M.; Cui, X.; Zhang, X. P.; de Bruin, B. 鈥淎 Metalloradical Approach to听2H-Chromenes鈥澨�J. Am. Chem. Soc.听2014,听136, 1090鈥�1096. []

87.听听Cui, X.; Zhang, X. P. 鈥淎symmetric C鈥揌 Functionalization by Transition Metal-Catalyzed Carbene Transfer Reactions鈥� In听Comprehensive Organic Synthesis II (Second Edition)听Eds. Knochel, P.; Molander, G.; Amsterdam: Elsevier,听2014, Vol. 7, pp. 86鈥�120. []

86.听听Maza, W. A.; Vetromile, G. M.; Kim, C.-S.; Xu, X.; Zhang, X. P.; Larsen, R. W. 鈥淪pectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II)porphyrins鈥澨�J. Phys. Chem. A.听2013,听117, 11308鈥�11315. []

85.听听Xu, X.; Zhu, S.-F.; Cui, X.; Wojtas, L.; Zhang, X. P. 鈥淐obalt(II)-Catalyzed Asymmetric Olefin Cyclopropanation with a-Ketodiazoacetates鈥澨�Angew. Chem. Int. Ed.听2013,听52, 11857鈥�11861. [] [Highlighted in听]

84.听听Paul, N. D.; Lu, H.-J.; Zhang, X. P.; de Bruin, B. 鈥淐arbene Radicals in Cobalt(II) Porphyrin-Catalyzed Carbene Carbonylation Reactions: A Catalytic Approach to Ketenes鈥澨�Chem. Eur. J.听2013,听19, 12953鈥�12958. []

83.听听Liu, L.; Xie, H.; Bostic, H. E.; Jin, L.-M.; Best, D. B.; Zhang, X. P.; Zhan, W. 鈥淓ffects of Oriented Surface Dipole on Photoconversion Efficiency in an Alkane/Lipid-Hybrid-Bilayer-Based Photovoltaic Model System鈥澨�ChemPhysChem听2013,听14, 2777鈥�2785. []

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80.听听Cui, X.; Xu, X.; Wojtas, L.; Kim, M. M.; Zhang, X. P. 鈥淩egioselective Synthesis of Multisubstituted Furans via Metalloradical Cyclization of Alkynes with alpha-Diazocarbonyls: Construction of Functionalized alpha-Oligofurans鈥澨�J. Am. Chem. Soc.听2012,听134, 19981鈥�19984. [] [Highlighted in听] [Highlighted in听]

79.听听Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. 鈥淪tereoselective Radical Amination of Electron-Deficient C(sp3)鈥揌 Bonds by Co(II)-Based Metalloradical Catalysis: Synthesis of alpha-Amino Acid Derivatives via alpha-C鈥揌 Amination of Esters and Amides鈥澨�Org. Lett.听2012,听14, 5158鈥�5161. []

78.听听Meng, L.; Cheng, Q.; Kim, C.-S.; Gao, W.-Y.; Wojtas, L.; Chen, Y.-S.; Zaworotko, M. J.; Zhang, X. P.; Ma, S.-Q. 鈥淐rystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker鈥澨�Angew. Chem. Int. Ed.听2012,听51, 10082鈥�10085. [] [Selected as听]

77.听听Jiang, H.-L.; Zhang, X. P. 鈥淥xidation: C鈹�N Bond Formation by Oxidation (Aziridines)鈥� In听Comprehensive Chirality; eds. Carreira, E. M.; Yamamoto, H.; Amsterdam: Elsevier,听2012, Vol. 5, pp. 168鈥�182. []听

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74.听听Zhu, S.-F.; Cui, X.; Zhang, X. P. 鈥淟igand Effect on Cobalt(II)-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Approaching High Stereoselectivity through Modular Design of D2-Symmetric Chiral Porphyrins鈥澨�Eur. J. Inorg. Chem.听2012, 430鈥�434. []

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72.听听Cui, X.; Zhang, X. P. 鈥淚ron(III) meso-Tetraphenylporphine Chloride鈥澨�e-EROS, John Wiley & Sons,听2012;听DOI: 10.1002/047084289X.rn01388. []

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